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3.2.1/3.2.2/3.2.3 Enthalpy changes, reaction rates and chemical equilibrium GapFill
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Reactions that give out or take in heat energy are said to be , respectively. Measuring the change in heat energy associated with a reaction relies on recording the temperature change in a substance of known mass and heat capacity. The heat released or absorbed during a process is closely tied to a quantity called the enthalpy change, represented by the symbol Δ . Often, enthalpy changes are measured under 'standard conditions', represented by a symbol. This term refers to a stated temperature, usually 298 K, and a pressure of , with an element's physical state under such conditions called its 'standard state'.
The rate of a chemical reaction is determined by the frequency with which reactant particles collide with both the correct orientation and with sufficient energy, the energy. Species that increase the rate of reaction without being used up themselves are called .
The equilibrium constant for a reversible reaction, written in terms of the concentrations of the reactants and products, is denoted by the symbol . More specifically, it is the product of the concentrations of the products the product of the concentrations of the reactants, with each species' concentration raised to the power of its stoichiometric coefficient in the chemical equation. The concentration of a given species X is always written in units of mol dm−3, and is represented by . For now, you will only be expected to write expressions for the equilibrium constants of reactions where all the reactants and products are in the same phase, which are described as . The effect of a change in conditions on the position of an equilibrium can be predicted using principle.