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Aromatic chemistry, amines and polymers GapFill

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C
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Benzene has the molecular formula   C6H6C6H10C6H12C6H14. Its molecules are flat rings, with each carbon atom contributing one electron from its   3p1s2s2p sub-shell to form a delocalised cloud of electrons above and below the ring. The enthalpy of   hydrogenationsolutionvaporisationatomisation of benzene is less exothermic than would be expected for three separate double bonds, implying something is making it more stable. Molecules containing a benzene ring are said to be '  fragrantsaturatedaromaticaliphatic', while the IUPAC prefix for a benzene ring is 'phenyl-'. Benzene undergoes electrophilic substitution reactions, such as nitration and Friedel−Crafts   oxidationacylationaminationhalogenation. The products of the latter reaction are   ketonesaldehydescarboxylic acidsamides.

Amines contain  a sulfuran oxygena nitrogena phosphorus atom with at least one alkyl or aromatic group attached. One method of synthesising aliphatic amines is to react ammonia with   alcoholsalkeneshalogenoalkanesnitriles.

This is an example of   electrophilic substitutionelectrophilic additionnucleophilic substitutionnucleophilic addition reaction.

Polyesters and polyamides are   condensationreductionprecipitationelimination polymers. They are formed from monomers with two functional groups; when the monomers react with one another, a small molecule is released, typically HCl or  COH2OH2CO2. Unlike addition polymers, these polymers can be broken down by bacteria (i.e. they are biodegradable) or by hydrolysis.

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Pass Mark
72%